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A mild and efficient rhenium-catalyzed transfer hydrogenation of terminal olefins using alcoholysis of amine-borane adducts as a reducing system


Dong, H; Berke, H (2011). A mild and efficient rhenium-catalyzed transfer hydrogenation of terminal olefins using alcoholysis of amine-borane adducts as a reducing system. Journal of Organometallic Chemistry, 696(9):1803-1808.

Abstract

ReBr(2)(NO)(CH(3)CN)(PTA)(2)] (PTA - 1, 3, 5-triaza-7-phosphaadamantane) catalyzes the alcoholysis of ammonia-borane and amine-boranes and the catalytic transfer hydrogenations of various terminal olefins. Excellent yields were achieved at 70 degrees C in isopropanol using tBuOK as a co-catalyst affording TOF values up to 396 h(-1). (C) 2011 Elsevier B.V. All rights reserved.

Abstract

ReBr(2)(NO)(CH(3)CN)(PTA)(2)] (PTA - 1, 3, 5-triaza-7-phosphaadamantane) catalyzes the alcoholysis of ammonia-borane and amine-boranes and the catalytic transfer hydrogenations of various terminal olefins. Excellent yields were achieved at 70 degrees C in isopropanol using tBuOK as a co-catalyst affording TOF values up to 396 h(-1). (C) 2011 Elsevier B.V. All rights reserved.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:May 2011
Deposited On:12 Mar 2012 16:09
Last Modified:05 Apr 2016 15:41
Publisher:Elsevier
ISSN:0022-328X
Publisher DOI:https://doi.org/10.1016/j.jorganchem.2011.01.027
Other Identification Number:ISI:000290019300013

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