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Amino olefin nickel(I) and nickel(0) complexes as dehydrogenation catalysts for amine boranes


Vogt, M; de Bruin, B; Berke, H; Trincado, M; Gruetzmacher, H (2011). Amino olefin nickel(I) and nickel(0) complexes as dehydrogenation catalysts for amine boranes. Chemical Science, 2(4):723-727.

Abstract

A rare paramagnetic organometallic nickel(I) olefin complex can be isolated using the ligand bis(5H-dibenzoa,d]cyclohepten-5-yl)amine. This complex and related nickel(0) hydride complexes show very high catalytic activity in the dehydrogenation of dimethylamino borane with release of one equivalent of dihydrogen.

Abstract

A rare paramagnetic organometallic nickel(I) olefin complex can be isolated using the ligand bis(5H-dibenzoa,d]cyclohepten-5-yl)amine. This complex and related nickel(0) hydride complexes show very high catalytic activity in the dehydrogenation of dimethylamino borane with release of one equivalent of dihydrogen.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2011
Deposited On:15 Mar 2012 07:57
Last Modified:17 Feb 2018 15:38
Publisher:Royal Society of Chemistry
ISSN:2041-6520
OA Status:Gold
Publisher DOI:https://doi.org/10.1039/c0sc00483a
Other Identification Number:ISI:000288387600021

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