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Attempted Abstraction of the Halogenides in (HNEt3)Re(CH3CN)(2)Cl-4] and Crystal Structures of cis-Re(CH3CN)(2)Cl-4] center dot CH3CN and cis-Re(NHC(OCH3)CH3)(2)Cl-4]


Kunz, Peter C; Kurz, Philipp; Spingler, Bernhard; Alberto, Roger (2007). Attempted Abstraction of the Halogenides in (HNEt3)Re(CH3CN)(2)Cl-4] and Crystal Structures of cis-Re(CH3CN)(2)Cl-4] center dot CH3CN and cis-Re(NHC(OCH3)CH3)(2)Cl-4]. Zeitschrift für Anorganische und Allgemeine Chemie, 633(15):2753-2756.

Abstract

The abstraction of the halogenide ligands in Re(CH3CN)(2)Cl-4](-) should result in a solvent-only stabilized Re-III complex. The reactions of salts of Re(CH3CN)(2)Cl-4](-) with silver(1) and thallium(I) salts were investigated and the solid-state structures of cis-Re(CH3CN)(2)Cl-4] center dot CH3CN and cisRe(NHC(OCH3)CH3)(2)Cl-4] are described.

Abstract

The abstraction of the halogenide ligands in Re(CH3CN)(2)Cl-4](-) should result in a solvent-only stabilized Re-III complex. The reactions of salts of Re(CH3CN)(2)Cl-4](-) with silver(1) and thallium(I) salts were investigated and the solid-state structures of cis-Re(CH3CN)(2)Cl-4] center dot CH3CN and cisRe(NHC(OCH3)CH3)(2)Cl-4] are described.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2007
Deposited On:23 Oct 2012 13:30
Last Modified:07 Dec 2017 15:40
Publisher:Wiley-Blackwell
ISSN:0044-2313
Publisher DOI:https://doi.org/10.1002/zaac.200700265
Other Identification Number:ISI:000250808900040

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