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Synthesis of heteroleptic pyrrolide/bipyridyl complexes of ruthenium(II)


Lundrigan, Travis; Jackson, Carla L M; Uddin, Md Imam; Tucker, Lloyd A; Ali, Adeeb Al-Sheikh; Linden, Anthony; Cameron, T Stanley; Thompson, Alison (2012). Synthesis of heteroleptic pyrrolide/bipyridyl complexes of ruthenium(II). Canadian Journal of Chemistry, 90(8):693-700.

Abstract

The synthesis and characterization of the first heteroleptic pyrrolide/2,2′-bipyridyl complexes of ruthenium(II) are reported. Pyrroles substituted at the 2-position with X = O functionality react with Ru(bipy)2Cl2·2H2O to form complexes in which the pyrrolide ligands chelate to Ru(II). The library of pyrroles includes 2-formyl, 2-keto, 2-carboxylato, 2-sulfinyl, and 2-sulfonyl derivatives.

Abstract

The synthesis and characterization of the first heteroleptic pyrrolide/2,2′-bipyridyl complexes of ruthenium(II) are reported. Pyrroles substituted at the 2-position with X = O functionality react with Ru(bipy)2Cl2·2H2O to form complexes in which the pyrrolide ligands chelate to Ru(II). The library of pyrroles includes 2-formyl, 2-keto, 2-carboxylato, 2-sulfinyl, and 2-sulfonyl derivatives.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2012
Deposited On:11 Dec 2012 16:55
Last Modified:07 Dec 2017 17:10
Publisher:NRC Research Press
Series Name:Canadian Journal of Chemistry
ISSN:0008-4042
Publisher DOI:https://doi.org/10.1139/v2012-045

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