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Basicity of (2,6-Pyridino)paracyclophanes: Lone pair-π, cation-π, and solvation effects


Baldridge, Kim K; Cozzi, Franco; Siegel, Jay S (2012). Basicity of (2,6-Pyridino)paracyclophanes: Lone pair-π, cation-π, and solvation effects. Angewandte Chemie Internationale Edition, 51(12):2903-2906.

Abstract

Lost in solvation: A study of the basicity of (2,6-pyridino)paracyclophanes (see picture; C light blue, N blue, S orange, F yellow, H green) reveals the importance of bulk solvation compared to cation–π effects in determining the relative stability of cations.

Abstract

Lost in solvation: A study of the basicity of (2,6-pyridino)paracyclophanes (see picture; C light blue, N blue, S orange, F yellow, H green) reveals the importance of bulk solvation compared to cation–π effects in determining the relative stability of cations.

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10 citations in Scopus®
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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2012
Deposited On:24 Jan 2013 15:49
Last Modified:07 Dec 2017 18:28
Publisher:Wiley-VCH Verlag
ISSN:1433-7851
Publisher DOI:https://doi.org/10.1002/anie.201108545

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