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Arenium acid catalyzed deuteration of aromatic hydrocarbons


Duttwyler, Simon; Butterfield, Anna M; Siegel, Jay S (2012). Arenium acid catalyzed deuteration of aromatic hydrocarbons. Journal of Organic Chemistry:121206145832008.

Abstract

The arenium acid [mesitylene–H]+ has been shown to be an extraordinarily active H/D exchange catalyst for the perdeuteration of polycyclic aromatic hydrocarbons. The reactions take place under ambient conditions in C6D6 as an inexpensive deuterium source. High isolated yields and excellent degrees of deuterium incorporation were achieved using the substrates p-terphenyl, fluoranthene, pyrene, triphenylene, and corannulene.

Abstract

The arenium acid [mesitylene–H]+ has been shown to be an extraordinarily active H/D exchange catalyst for the perdeuteration of polycyclic aromatic hydrocarbons. The reactions take place under ambient conditions in C6D6 as an inexpensive deuterium source. High isolated yields and excellent degrees of deuterium incorporation were achieved using the substrates p-terphenyl, fluoranthene, pyrene, triphenylene, and corannulene.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:19 November 2012
Deposited On:18 Feb 2013 16:02
Last Modified:07 Dec 2017 19:28
Publisher:American Chemical Society
ISSN:0022-3263
Publisher DOI:https://doi.org/10.1021/jo302201a

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