Header

UZH-Logo

Maintenance Infos

Sulfur addition to aldimines: thioamides, not thiaziridines, as products; revision of an old report


Mloston, Grzegorz; Depczynski, Robert; Woznicka, Marta; Laur, Peter; Englert, Ulli; Hu, Chunhua; Heimgartner, Heinz (2005). Sulfur addition to aldimines: thioamides, not thiaziridines, as products; revision of an old report. Journal of Sulfur Chemistry, 26(2):111-117.

Abstract

The reaction of 4-(phenylimino)butan-2-ol with ammonium polysulfide in refluxing EtOH yields 3-hydroxy-N-phenylbutanethioamide as the only isolated product. The structure has been established by single-crystal X-ray diffraction. Treatment of N-benzylidenamines with ammonium polysulfide has proven a general method for the preparation of thiobenzamides.

Abstract

The reaction of 4-(phenylimino)butan-2-ol with ammonium polysulfide in refluxing EtOH yields 3-hydroxy-N-phenylbutanethioamide as the only isolated product. The structure has been established by single-crystal X-ray diffraction. Treatment of N-benzylidenamines with ammonium polysulfide has proven a general method for the preparation of thiobenzamides.

Statistics

Citations

Dimensions.ai Metrics

Altmetrics

Downloads

129 downloads since deposited on 25 Apr 2013
18 downloads since 12 months
Detailed statistics

Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:April 2005
Deposited On:25 Apr 2013 09:44
Last Modified:18 Apr 2018 11:43
Publisher:Taylor & Francis
ISSN:1741-5993
Funders:Polish State Committee for Scientific Research (Grant No. 4 T09A 046 25), F. Hoffmann-La Roche AG, Basel
Additional Information:This is an Author's Accepted Manuscript of an article published in Mloston, Grzegorz; Depczynski, Robert; Woznicka , Marta; Laur, Peter; Englert, Ulli; Hu, Chunhua; Heimgartner, Heinz (2005). Sulfur addition to aldimines: thioamides, not thiaziridines, as products; revision of an old report. Journal of Sulfur Chemistry, 26(2):111-117. Copyright Taylor & Francis, available online at: http://www.tandfonline.com/10.1080/17415990500056788
OA Status:Green
Publisher DOI:https://doi.org/10.1080/17415990500056788

Download