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Synthesis of a Novel Heterospirocyclic 3-(N-Methyl-N-phenylamino)-2H-azirine and its Use as an Amino Acid Equivalent in the Preparation of a Model Tripeptide


Villalgordo, Jose M; Heimgartner, Heinz (1993). Synthesis of a Novel Heterospirocyclic 3-(N-Methyl-N-phenylamino)-2H-azirine and its Use as an Amino Acid Equivalent in the Preparation of a Model Tripeptide. Tetrahedron, 49:7215-7222.

Abstract

The synthesis of a novel heterospirocyclic 3-amino-2H-azirine based on the reaction between amide enolates and diphenylphosphorochloridate is described. This compound has been shown to be a useful amino acid equivalent and the synthesis of a model tripeptide was achieved in good overall yields.

Abstract

The synthesis of a novel heterospirocyclic 3-amino-2H-azirine based on the reaction between amide enolates and diphenylphosphorochloridate is described. This compound has been shown to be a useful amino acid equivalent and the synthesis of a model tripeptide was achieved in good overall yields.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:1993
Deposited On:26 Dec 2013 09:47
Last Modified:18 Apr 2018 11:44
Publisher:Elsevier
ISSN:0040-4020
Funders:Swiss National Science Foundation, F. Hoffmann-La Roche AG, Basel
OA Status:Closed
Publisher DOI:https://doi.org/10.1016/S0040-4020(01)87199-4
Project Information:
  • : FunderSNSF
  • : Grant ID
  • : Project TitleSwiss National Science Foundation
  • : Funder
  • : Grant ID
  • : Project TitleF. Hoffmann-La Roche AG, Basel

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