Header

UZH-Logo

Maintenance Infos

3-(Acylamino)-3-amino-2-nitroacrylonitriles from N-Acyl-S-methyl-3,3-diamino-2-nitroacrylthioimidates


Garcia Trimino, Maria I; Linden, Anthony; Heimgartner, Heinz; Macias Cabrera, Arturo (1993). 3-(Acylamino)-3-amino-2-nitroacrylonitriles from N-Acyl-S-methyl-3,3-diamino-2-nitroacrylthioimidates. Helvetica Chimica Acta, 76:2817-2829.

Abstract

Reaction of N-acyI-3,3-diamino-2-nitroacrylthioamides 1 with MeI at room temperature leads to N-acyl-S-methyl-3,3-diamino-2-nitroacrylthioimidates 2 in moderate yields. The latter react with Hg(OAc)2 in DMF yielding 3-(acylamino)-3-amino-2-nitroacrylonitriles 8. The structures of 2a and 8a were established by X-ray crystallography.

Abstract

Reaction of N-acyI-3,3-diamino-2-nitroacrylthioamides 1 with MeI at room temperature leads to N-acyl-S-methyl-3,3-diamino-2-nitroacrylthioimidates 2 in moderate yields. The latter react with Hg(OAc)2 in DMF yielding 3-(acylamino)-3-amino-2-nitroacrylonitriles 8. The structures of 2a and 8a were established by X-ray crystallography.

Statistics

Citations

6 citations in Web of Science®
8 citations in Scopus®
Google Scholar™

Altmetrics

Downloads

0 downloads since deposited on 26 Dec 2013
0 downloads since 12 months

Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:1993
Deposited On:26 Dec 2013 09:44
Last Modified:26 Jan 2017 08:55
Publisher:Wiley-Blackwell
ISSN:0018-019X
Funders:Swiss Federal Government (National Scholarship for Foreign Students)
Publisher DOI:https://doi.org/10.1002/hlca.19930760808

Download