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Reaction of Diphenyl Phosphorochloridate with Amide Enolates: A New and Convenient Synthesis of 2-Monosubstituted 3-(N-Methyl-N-phenylamino)-2H-azirines


Villalgordo, Jose M; Heimgartner, Heinz (1992). Reaction of Diphenyl Phosphorochloridate with Amide Enolates: A New and Convenient Synthesis of 2-Monosubstituted 3-(N-Methyl-N-phenylamino)-2H-azirines. Helvetica Chimica Acta, 75:1866-1871.

Abstract

Reaction of diphenyl phosphorochloridate with amide enolates and subsequent treatment with NaN3 leads to 2-monosubstituted 3-amino-2H-azirines 5 in moderate yields. The reactivity of these azirines is briefly explored.

Abstract

Reaction of diphenyl phosphorochloridate with amide enolates and subsequent treatment with NaN3 leads to 2-monosubstituted 3-amino-2H-azirines 5 in moderate yields. The reactivity of these azirines is briefly explored.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:1992
Deposited On:03 Jan 2014 07:03
Last Modified:26 Jan 2017 08:55
Publisher:Wiley-Blackwell
ISSN:0018-019X
Funders:Swiss National Science Foundation, F. Hoffmann-La Roche AG, Basel
Publisher DOI:https://doi.org/10.1002/hlca.19920750612

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