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Catalytic Michael reactions of ketoesters with a camphor-derived acrylate equivalent: stereoselective access to all-carbon quaternary centers


Palomo, C; Oiarbide, M; García, J M; Bañuelos, P; Odriozola, J M; Razkin, J; Linden, A (2008). Catalytic Michael reactions of ketoesters with a camphor-derived acrylate equivalent: stereoselective access to all-carbon quaternary centers. Organic Letters, 10(13):2637-2640.

Abstract

A camphor-based alpha'-hydroxy enone reagent acts as a chiral acrylate equivalent in copper-catalyzed Michael reactions of beta-keto esters and affords products that possess all-carbon quaternary stereocenters of high enantiomeric purity.

Abstract

A camphor-based alpha'-hydroxy enone reagent acts as a chiral acrylate equivalent in copper-catalyzed Michael reactions of beta-keto esters and affords products that possess all-carbon quaternary stereocenters of high enantiomeric purity.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2008
Deposited On:19 Jan 2009 16:03
Last Modified:21 Nov 2017 13:45
Publisher:American Chemical Society
ISSN:1523-7052
Funders:Universidad del Paı´s Vasco, Gobierno Vasco, MEC, UPNA
Publisher DOI:https://doi.org/10.1021/ol800564d
PubMed ID:18517215

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