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Synthesis and solvatochromic fluorescence of biaryl pyrimidine nucleosides


Mata, Guillaume; Luedtke, Nathan W (2013). Synthesis and solvatochromic fluorescence of biaryl pyrimidine nucleosides. Organic Letters, 15(10):2462-2465.

Abstract

Fluorescent pyrimidine analogs containing a fused biphenyl unit were prepared in high yields using stereoselective N-glycosylation and Suzuki–Miyaura cross-coupling reactions. The resulting “push–pull” fluorophores exhibit highly solvatochromic emissions from twisted intramolecular charge-transfer (TICT) states.

Abstract

Fluorescent pyrimidine analogs containing a fused biphenyl unit were prepared in high yields using stereoselective N-glycosylation and Suzuki–Miyaura cross-coupling reactions. The resulting “push–pull” fluorophores exhibit highly solvatochromic emissions from twisted intramolecular charge-transfer (TICT) states.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2013
Deposited On:15 Jan 2014 12:08
Last Modified:16 Feb 2018 18:59
Publisher:American Chemical Society
ISSN:1523-7052
Additional Information:This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/ol400930s
OA Status:Green
Publisher DOI:https://doi.org/10.1021/ol400930s

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