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Synthesis of aryl-substituted 2-pyridyl-1,10-phenanthrolines : a series of oriented terpyridine analogues


Klosterman, J K; Linden, A; Siegel, J S (2008). Synthesis of aryl-substituted 2-pyridyl-1,10-phenanthrolines : a series of oriented terpyridine analogues. Organic & Biomolecular Chemistry, 6(15):2755-2764.

Abstract

A 3 × 3 matrix of manisyl (4-methoxy-2,6-dimethylphenyl) substituted pyridyl-1,10-phenanthrolines has been synthesized by utilizing a general palladium catalyzed cross-coupling procedure. The directionality of these terdentate ligands will generate chiral octahedral ML2 complexes, potentially useful for the metal templated synthesis of topologically chiral structures.

Abstract

A 3 × 3 matrix of manisyl (4-methoxy-2,6-dimethylphenyl) substituted pyridyl-1,10-phenanthrolines has been synthesized by utilizing a general palladium catalyzed cross-coupling procedure. The directionality of these terdentate ligands will generate chiral octahedral ML2 complexes, potentially useful for the metal templated synthesis of topologically chiral structures.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:August 2008
Deposited On:19 Jan 2009 11:12
Last Modified:05 Apr 2016 12:46
Publisher:Royal Society of Chemistry
ISSN:1477-0520
Additional Information:Persons who receive the PDF must not make it further available or distribute it.
Publisher DOI:https://doi.org/10.1039/b804106g
PubMed ID:18633533

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