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Towards Molecular Ribbons of Corannulene


Furrer, Fabienne; Linden, Anthony; Stuparu, Mihaiela C (2013). Towards Molecular Ribbons of Corannulene. Chemistry - A European Journal, 19(39):13199-13206.

Abstract

Herein, we explore the synthesis of corannulene-based ribbon-shaped molecules through a repetitive Diels–Alder strategy. For this process, appropriate corannulene-based dienes and dienophiles were identified and synthesized. These building blocks could be combined in a modular way to obtain the dimeric and trimeric segments of the hypothetical molecular ribbons. 1D and 2D NMR measurements, along with crystal-structure analyses, allowed the structures and geometries of the synthesized compounds to be determined.

Abstract

Herein, we explore the synthesis of corannulene-based ribbon-shaped molecules through a repetitive Diels–Alder strategy. For this process, appropriate corannulene-based dienes and dienophiles were identified and synthesized. These building blocks could be combined in a modular way to obtain the dimeric and trimeric segments of the hypothetical molecular ribbons. 1D and 2D NMR measurements, along with crystal-structure analyses, allowed the structures and geometries of the synthesized compounds to be determined.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2013
Deposited On:20 Feb 2014 08:29
Last Modified:05 Apr 2016 17:42
Publisher:Wiley-VCH Verlag Berlin
ISSN:0947-6539
Funders:Ambizione (PZ00P2- 126615) of the Swiss National Science Foundation
Publisher DOI:https://doi.org/10.1002/chem.201300830

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