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Eine neue 1,3-Oxathiolan-Synthese: Spirocyclische 1,3-0xathiolane aus der Lewis-Säure katalysierten Umsetzung von 1,3-Thiazol-5(4H)-thionen mit Oxiranen


Tromm, Peter-Claus; Heimgartner, Heinz (1990). Eine neue 1,3-Oxathiolan-Synthese: Spirocyclische 1,3-0xathiolane aus der Lewis-Säure katalysierten Umsetzung von 1,3-Thiazol-5(4H)-thionen mit Oxiranen. Helvetica Chimica Acta, 73(8):2287-2294.

Abstract

The BF3.Et2O-catalyzed reaction of 2,4,4-trisubstituted 1,3-thiazole-5(4H)-thiones 13 with alkyl- and phenyl-substituted oxiranes 7 in CH2Cl2 at room temperature leads, in very good yields, to 1-oxa-4,6-dithia-8- azaspiro[4.4]non-7-enes 14 and 15.

Abstract

The BF3.Et2O-catalyzed reaction of 2,4,4-trisubstituted 1,3-thiazole-5(4H)-thiones 13 with alkyl- and phenyl-substituted oxiranes 7 in CH2Cl2 at room temperature leads, in very good yields, to 1-oxa-4,6-dithia-8- azaspiro[4.4]non-7-enes 14 and 15.

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Additional indexing

Other titles:A New 1,3-Oxathiolane Synthesis: Spirocyclic 1,3-Oxathiolanes from the Lewis-Acid-Catalyzed Reaction of 1,3-Thiazole-5(4H)-thiones and Oxiranes
Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:German
Date:1990
Deposited On:27 Mar 2014 10:48
Last Modified:05 Apr 2016 17:46
Publisher:Wiley-Blackwell
ISSN:0018-019X
Funders:Schweizerischer Nationalfonds zur Förderung der wissenschaftlichen Forschung, F. Hoffmann-La Roche AG, Basel
Publisher DOI:https://doi.org/10.1002/hlca.19900730825

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