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Thioaldehyde and Thioketone S-Sulfides (Thiosulfines)


Mloston, Grzegorz; Heimgartner, Heinz (2014). Thioaldehyde and Thioketone S-Sulfides (Thiosulfines). In: Bronsted Nielsen, M; Krause, N; Marek, I; Schaumann, E; Wirth, T. Science of Synthesis Knowledge Updates: 2014/2. Stuttgart: Thieme Verlag, 403-411.

Abstract

The manuscript is an overview on methods for the in situ generation and applications of highly reactive thiocarbonyl S-sulfides. Typically, they react as sulfur rich 1,3-dipoles and trap both electron deficient C,C dipolarophiles and thiocarbonyl substrates yielding the corresponding five membered cycloadducts. In some instances, intermediate thiocarbonyl S-sulfides and/or their cyclic isomers, i.e. dithiiranes, act as sulfur transferring agents leading to sulfur rich heterocyles (pentathiepanes, hexathiepanes, etc.).

Abstract

The manuscript is an overview on methods for the in situ generation and applications of highly reactive thiocarbonyl S-sulfides. Typically, they react as sulfur rich 1,3-dipoles and trap both electron deficient C,C dipolarophiles and thiocarbonyl substrates yielding the corresponding five membered cycloadducts. In some instances, intermediate thiocarbonyl S-sulfides and/or their cyclic isomers, i.e. dithiiranes, act as sulfur transferring agents leading to sulfur rich heterocyles (pentathiepanes, hexathiepanes, etc.).

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Additional indexing

Item Type:Book Section, not refereed, further contribution
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2014
Deposited On:10 Jun 2014 12:34
Last Modified:21 Nov 2017 17:22
Publisher:Thieme Verlag
ISBN:978-3-1317-6261-0
Related URLs:https://www.thieme.de/shop/Houben-Weyl--SoS/Science-of-Synthesis-Knowledge-Updates-9783131762610/p/000000000283414401

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