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Thioaldehyde and Thioketone S-Oxides and S-Imides (Sulfines and Derivatives) (Update 2014)


Mloston, Grzegorz; Heimgartner, Heinz (2014). Thioaldehyde and Thioketone S-Oxides and S-Imides (Sulfines and Derivatives) (Update 2014). In: Bronsted Nielsen, M; Krause, N; Marek, I; Schaumann, E; Wirth, T. Science of Synthesis Knowledge Updates: 2014/2. Stuttgart: Thieme Verlag, 393-401.

Abstract

The manuscript is an update to the earlier Science of Synthesis contribution describing methods for the synthesis and new applications of thiocarbonyl S-oxides (sulfines) and thiocarbonyl S-imides. In general, thiocarbonyl S-oxides are more stable and in many instances they can be isolated in substance. The in situ generated thiocarbonyl S-imides are efficient ‘sulfur transferring agents’ via the isomeric thiaziridines formed as products of electrocyclic ring closure. Stable thiocarbonyl S-imides, derived form hexafluorothioacetone, are useful 1,3-dipoles applied for the preparation of fluorinated, five-membered heterocycles.

Abstract

The manuscript is an update to the earlier Science of Synthesis contribution describing methods for the synthesis and new applications of thiocarbonyl S-oxides (sulfines) and thiocarbonyl S-imides. In general, thiocarbonyl S-oxides are more stable and in many instances they can be isolated in substance. The in situ generated thiocarbonyl S-imides are efficient ‘sulfur transferring agents’ via the isomeric thiaziridines formed as products of electrocyclic ring closure. Stable thiocarbonyl S-imides, derived form hexafluorothioacetone, are useful 1,3-dipoles applied for the preparation of fluorinated, five-membered heterocycles.

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Item Type:Book Section, not_refereed, further contribution
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2014
Deposited On:10 Jun 2014 12:36
Last Modified:14 Feb 2018 21:17
Publisher:Thieme Verlag
ISBN:978-3-1317-6261-0
OA Status:Closed
Related URLs:https://www.thieme.de/shop/Houben-Weyl--SoS/Science-of-Synthesis-Knowledge-Updates-9783131762610/p/000000000283414401

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