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Kristallstruktur eines Tetrahydro-1(1H)-isoindolons


Prewo, Roland; Bieri, Jost H; Widmer, Ulrich; Heimgartner, Heinz (1981). Kristallstruktur eines Tetrahydro-1(1H)-isoindolons. Helvetica Chimica Acta, 64(5):1515-1521.

Abstract

Crystal Structure of a Tetrahydro-1(1H)-isoindolone.
The structure of the tetrahydro-1(1H)-isoindolone 4a, the product of an intra- molecular Diels-Alder addition, has been determined by X-ray analysis. The revised relative configuration of 4a suggests a formation via the exo-transition state of the [4+2]-cycloaddition, followed by enolization to the more stable cis-fused product.

Abstract

Crystal Structure of a Tetrahydro-1(1H)-isoindolone.
The structure of the tetrahydro-1(1H)-isoindolone 4a, the product of an intra- molecular Diels-Alder addition, has been determined by X-ray analysis. The revised relative configuration of 4a suggests a formation via the exo-transition state of the [4+2]-cycloaddition, followed by enolization to the more stable cis-fused product.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:German
Date:1981
Deposited On:24 Jul 2014 07:26
Last Modified:21 Nov 2017 17:24
Publisher:Wiley-Blackwell
ISSN:0018-019X

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