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Identifying Photoreaction Products in Cinnamate-Based Photoalignment Materials


Adams, Donat J; Chappellet, Sabrina; Lincker, Frederic; Ibn-Elhaj, Mohammed; Watts, Benjamin; Iannuzzi, Marcella; Jung, Dubravka Sisak; Pignedoli, Carlo A; Passerone, Daniele (2014). Identifying Photoreaction Products in Cinnamate-Based Photoalignment Materials. Journal of Physical Chemistry C, 118(28):15422-15433.

Abstract

A novel joint computational and experimental strategy is developed and applied for the detection and the identification of photoreaction products in cinnamate-based photoalignment materials. Based on NEXAFS, IR, and NMR spectroscopies and supported by computer simulation tools, this structural analysis method allows distinguishing the typical signatures of products resulting from UV-induced photoreactions between isomers of cinnamate-based model compounds. Besides deepening the understanding of typical photoalignment reaction products, the proposed strategy acquires technological relevance in supporting the realization of next generation materials for the LCD panel industry.

Abstract

A novel joint computational and experimental strategy is developed and applied for the detection and the identification of photoreaction products in cinnamate-based photoalignment materials. Based on NEXAFS, IR, and NMR spectroscopies and supported by computer simulation tools, this structural analysis method allows distinguishing the typical signatures of products resulting from UV-induced photoreactions between isomers of cinnamate-based model compounds. Besides deepening the understanding of typical photoalignment reaction products, the proposed strategy acquires technological relevance in supporting the realization of next generation materials for the LCD panel industry.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Date:2014
Deposited On:10 Dec 2014 17:17
Last Modified:05 Apr 2016 18:23
Publisher:American Chemical Society
ISSN:1932-7447
Additional Information:This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Physical Chemistry C, copyright © American Chemical Society after peer review and technical editing by the publisher.
Publisher DOI:https://doi.org/10.1021/jp504765f

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