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Thermolyse des 1:1-Adduktes aus ‘Münchnon’ und Cyclopentadienchinon


Lukac, Josef; Heimgartner, Heinz; Schmid, Hans (1977). Thermolyse des 1:1-Adduktes aus ‘Münchnon’ und Cyclopentadienchinon. CHIMIA International Journal for Chemistry, 31:138-139.

Abstract

The thermolysis of the 1:1-cycloadduct 3, synthesized by the addition of cyclopentadienequinone (1) and 3-methyl-2,4-diphenyl-5-oxazolone (2), yields 5,6-dihydro-2-methyl-1,3-diphenyl-2H-isoindol-4,7-dione (5) and not the tetracyclic ketone 4 (cf. [2]). The structure of 5 is elucidated by spectral data and by dehydrogenation to the 2H-isoindole-4,7-dione 6.

Abstract

The thermolysis of the 1:1-cycloadduct 3, synthesized by the addition of cyclopentadienequinone (1) and 3-methyl-2,4-diphenyl-5-oxazolone (2), yields 5,6-dihydro-2-methyl-1,3-diphenyl-2H-isoindol-4,7-dione (5) and not the tetracyclic ketone 4 (cf. [2]). The structure of 5 is elucidated by spectral data and by dehydrogenation to the 2H-isoindole-4,7-dione 6.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:German
Date:1977
Deposited On:29 Oct 2014 13:13
Last Modified:18 Apr 2018 11:45
Publisher:Swiss Chemical Society
ISSN:0009-4293
Funders:Schweizerischer Nationalfonds zur Förderung der wissenschaftlichen Forschung
Additional Information:Copyright ©Swiss Chemical Society: CHIMIA, 31, 138-139, 1977
OA Status:Green
Project Information:
  • : FunderSNSF
  • : Grant ID
  • : Project TitleSchweizerischer Nationalfonds zur Förderung der wissenschaftlichen Forschung

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