Publication: Optically active imidazoles derived from enantiomerically pure trans-1,2-diaminocyclohexane
Optically active imidazoles derived from enantiomerically pure trans-1,2-diaminocyclohexane
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Mlostoń, G., Rygielska, D., Jasiński, M., & Heimgartner, H. (2011). Optically active imidazoles derived from enantiomerically pure trans-1,2-diaminocyclohexane. Tetrahedron: Asymmetry, 22, 669–674. https://doi.org/10.1016/j.tetasy.2011.04.005
Abstract
Abstract
Abstract
A new exploration of some monoprotected derivatives of trans-1,2-diaminocyclohexane as a platform for the synthesis of enantiomerically pure imidazole derivatives is described. The primary amino group (-NH2), present in the mono-imine derivative of salicylic aldehyde (hemi-salen derivative) 5 was used for sequential reactions with formaldehyde and a corresponding α-(hydroxyimino)ketone. (S)-(–)-1-Phenylethylamine was also used as starting material for the preparation of new imidazole N-oxides 7c and 10a-c, bearing a chiral N-(1-phenyl
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- Rygielska, D
- Jasiński, M
- Heimgartner, H
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Mlostoń, G., Rygielska, D., Jasiński, M., & Heimgartner, H. (2011). Optically active imidazoles derived from enantiomerically pure trans-1,2-diaminocyclohexane. Tetrahedron: Asymmetry, 22, 669–674. https://doi.org/10.1016/j.tetasy.2011.04.005
