Publication: Cytotoxicity of ruthenium(II) piano-stool complexes with imidazole-based PN ligands
Cytotoxicity of ruthenium(II) piano-stool complexes with imidazole-based PN ligands
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Huber, W., Broehler, P., Waetjen, W., Frank, W., Spingler, B., & Kunz, P. C. (2012). Cytotoxicity of ruthenium(II) piano-stool complexes with imidazole-based PN ligands. Journal of Organometallic Chemistry, 717, 187–194. https://doi.org/10.1016/j.jorganchem.2012.06.027
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A series of p-cymene ruthenium(II) complexes with imidazol-2-yl phosphines as PN ligands was prepared. Depending on the number of imidazolyl substituents in the ligands Ph3-nP(im)(n) {1-3: n = 1-3, im imidazol-2-yl (a), 1-methylimidazol-2-yl (b)} different coordination modes were observed: kappa P, kappa N-2,N or kappa N-3,N,N. The complexes were tested for their cytotoxicity in different cancer cell lines. Most of the compounds were found to be non-toxic; The compounds (p-cymene)Ru(1a)Cl-2] (4a) shows cytotoxicity towards A2780sens a
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- Huber, Wilhelm
- Broehler, Philip
- Waetjen, Wim
- Frank, Walter
- Kunz, Peter C
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Huber, W., Broehler, P., Waetjen, W., Frank, W., Spingler, B., & Kunz, P. C. (2012). Cytotoxicity of ruthenium(II) piano-stool complexes with imidazole-based PN ligands. Journal of Organometallic Chemistry, 717, 187–194. https://doi.org/10.1016/j.jorganchem.2012.06.027
