Publication: Vibrational dynamics of iron pentacarbonyl [Fe(CO)5] in liquid alkanes revisited
Vibrational dynamics of iron pentacarbonyl [Fe(CO)5] in liquid alkanes revisited
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Jouan, A., Jonusas, M., Vincent, J., Bernhardt, S., Tauvy, M., Jacquart, M., Helbing, J., Chin, W., & Crépin, C. (2025). Vibrational dynamics of iron pentacarbonyl [Fe(CO)5] in liquid alkanes revisited. Journal of Chemical Physics, 162(23), 234305. https://doi.org/10.1063/5.0266728
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We explore the solvent-dependence of the vibrational dynamics of Fe(CO)5 (IPC) using a novel 2D-IR setup. A 320 pixel MCT camera allows us to achieve high spectral resolution within a large detection window, which can be matched in excitation by scanning coherence times of up to 250 ps. The dynamics of the IR active modes of IPC in the C≡O stretching range are probed in a series of alkanes of different chain lengths and viscosities. 2D-IR maps at short waiting times reveal the detailed anharmonic structure of the modes at play: we det
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Jouan, A., Jonusas, M., Vincent, J., Bernhardt, S., Tauvy, M., Jacquart, M., Helbing, J., Chin, W., & Crépin, C. (2025). Vibrational dynamics of iron pentacarbonyl [Fe(CO)5] in liquid alkanes revisited. Journal of Chemical Physics, 162(23), 234305. https://doi.org/10.1063/5.0266728
