Publication: Mechanistic Insights into C(sp2)−C(sp)N Reductive Elimination from Gold(III) Cyanide Complexes
Mechanistic Insights into C(sp2)−C(sp)N Reductive Elimination from Gold(III) Cyanide Complexes
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Genoux, A., González, J. A., Merino, E., & Nevado, C. (2020). Mechanistic Insights into C(sp2)−C(sp)N Reductive Elimination from Gold(III) Cyanide Complexes. Angewandte Chemie Internationale Edition, 59, 17881–17886. https://doi.org/10.1002/anie.202005731
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A new family of phosphine‐ligated dicyanoarylgold(III) complexes has been prepared and their reactivity towards reductive elimination has been studied in detail. Both, a highly positive entropy of activation and a primary 12/13C KIE suggest a late concerted transition state while Hammett analysis and DFT calculations indicate that the process is asynchronous. As a result, a distinct mechanism involving an asynchronous concerted reductive elimination for the overall C(sp2)−C(sp)N bond forming reaction is characterized herein, for the f
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- Genoux, Alexandre
- González, Jorge A
- Merino, Estíbaliz
- Nevado, Cristina
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Genoux, A., González, J. A., Merino, E., & Nevado, C. (2020). Mechanistic Insights into C(sp2)−C(sp)N Reductive Elimination from Gold(III) Cyanide Complexes. Angewandte Chemie Internationale Edition, 59, 17881–17886. https://doi.org/10.1002/anie.202005731
