Publication: A click approach to structurally diverse conjugates containing a central di-1,2,3-triazole metal chelate
A click approach to structurally diverse conjugates containing a central di-1,2,3-triazole metal chelate
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Mindt, T. L., Schweinsberg, C., Brans, L., Hagenbach, A., Abram, U., Tourwé, D., Garcia-Garayoa, E., & Schibli, R. (2009). A click approach to structurally diverse conjugates containing a central di-1,2,3-triazole metal chelate. ChemMedChem, 4, 529–539. https://doi.org/10.1002/cmdc.200800418
Abstract
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Abstract
The selective and efficient synthesis of novel tridentate metal chelating systems containing two 1,4-disubstituted 1,2,3-triazole heterocycles obtained via the copper(I)-catalyzed cycloaddition of alkynes and azides (click reaction) is described. The constructs are shown to be efficient ligand systems for the chelation of fac-M(CO)(3)(H(2)O)(3) (M=(99m)Tc, Re) yielding well- defined and stable complexes. The organometallic (99m)Tc conjugates are suitable for application as diagnostic radiotracers for single photon emission comput
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- Mindt, T L
- Schweinsberg, C
- Brans, L
- Hagenbach, A
- Abram, U
- Tourwé, D
- Garcia-Garayoa, E
- Schibli, R
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Mindt, T. L., Schweinsberg, C., Brans, L., Hagenbach, A., Abram, U., Tourwé, D., Garcia-Garayoa, E., & Schibli, R. (2009). A click approach to structurally diverse conjugates containing a central di-1,2,3-triazole metal chelate. ChemMedChem, 4, 529–539. https://doi.org/10.1002/cmdc.200800418