Publication: Structure and Catalytic Properties of Homo- and Heterometallic Iron(II)-Based Di(2-pyridyl)ketone Oxoclusters
Structure and Catalytic Properties of Homo- and Heterometallic Iron(II)-Based Di(2-pyridyl)ketone Oxoclusters
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Civettini, D. R., Triana, C. A., De Jong, T. F., Abbott, D. F., Dürr, R. N., Luber, S., Mougel, V., & Patzke, G. R. (2025). Structure and Catalytic Properties of Homo- and Heterometallic Iron(II)-Based Di(2-pyridyl)ketone Oxoclusters. Journal of the American Chemical Society, 147(30), 26338–26351. https://doi.org/10.1021/jacs.5c04262
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Electrochemical water splitting is essential for reducing our dependence on fossil fuels through green hydrogen production and requires the design of new, low-cost, 3d transition-metal-based catalysts for the sluggish oxygen evolution reaction (OER). We report on the synthesis, characterization, and OER performance of new types of homo- and heterometallic iron(II)-based di(2-pyridyl)ketone cubanes, 1-[Fe(dpy-C{OH}O)(OAc)(HO)]ClO and 2-[FeNi(dpy-C{OH}O)(OAc)]ClO (dpy = di(2-pyridyl)diol), referred to as 1-{FeO} and 2-{FeNiO}. The heter
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Civettini, D. R., Triana, C. A., De Jong, T. F., Abbott, D. F., Dürr, R. N., Luber, S., Mougel, V., & Patzke, G. R. (2025). Structure and Catalytic Properties of Homo- and Heterometallic Iron(II)-Based Di(2-pyridyl)ketone Oxoclusters. Journal of the American Chemical Society, 147(30), 26338–26351. https://doi.org/10.1021/jacs.5c04262