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New Polycyclic Compounds from Photochemical Rearrangements of Some Substituted 2-Azatricyclo[5.2.2.0]undeca-4,8,10-trien-3-ones

Date

Date

Date
1991
Journal Article
Published version

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Mihova, T. R., Trifonov, L. S., Dimitrov, V. S., Orahovats, A. S., Linden, A., & Heimgartner, H. (1991). New Polycyclic Compounds from Photochemical Rearrangements of Some Substituted 2-Azatricyclo[5.2.2.0]undeca-4,8,10-trien-3-ones. Helvetica Chimica Acta, 74(5), 1011–1026. https://doi.org/10.1002/hlca.19910740512

Abstract

Abstract

Abstract

The products formed on UV irradiation of several tricyclic compounds (i.e. 3, 6, 8, 15, and 17, Schemes 2 - 4 ) were studied in detail. A marked dependence of the reaction course on the type and site of substitution was found. Among the several light-induced transformations, a novel rearrangement, i.e. 11 to 9 (Scheme 3) was identified. The formation of the polycyclic compound 13 on irradiation of 8a (Scheme 3) resulted from an unexpected skeletal rearrangement with dearomatization of one benzene ring. The structures of compounds 10,

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Acq. date: 2025-11-13

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121 since deposited on 2014-03-13
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Additional indexing

Creators (Authors)

  • Mihova, Tonya R
    affiliation.icon.alt
  • Trifonov, Latchezar S
    affiliation.icon.alt
  • Dimitrov, Valentin S
    affiliation.icon.alt
  • Orahovats, Alexander S
    affiliation.icon.alt
  • Heimgartner, Heinz
    affiliation.icon.alt

Journal/Series Title

Journal/Series Title

Journal/Series Title

Volume

Volume

Volume
74

Number

Number

Number
5

Page range/Item number

Page range/Item number

Page range/Item number
1011

Page end

Page end

Page end
1026

Item Type

Item Type

Item Type
Journal Article

Dewey Decimal Classifikation

Dewey Decimal Classifikation

Dewey Decimal Classifikation

Keywords

Physical and Theoretical Chemistry, Inorganic Chemistry, Organic Chemistry, Biochemistry, Drug Discovery, Catalysis

Language

Language

Language
English

Publication date

Publication date

Publication date
1991

Date available

Date available

Date available
2014-03-13

Publisher

Publisher

Publisher

ISSN or e-ISSN

ISSN or e-ISSN

ISSN or e-ISSN
0018-019X

OA Status

OA Status

OA Status
Closed

Free Access at

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Downloads

1 since deposited on 2014-03-13
Acq. date: 2025-11-13

Views

121 since deposited on 2014-03-13
Acq. date: 2025-11-13

Citations

Citation copied

Mihova, T. R., Trifonov, L. S., Dimitrov, V. S., Orahovats, A. S., Linden, A., & Heimgartner, H. (1991). New Polycyclic Compounds from Photochemical Rearrangements of Some Substituted 2-Azatricyclo[5.2.2.0]undeca-4,8,10-trien-3-ones. Helvetica Chimica Acta, 74(5), 1011–1026. https://doi.org/10.1002/hlca.19910740512

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