Publication: A novel benzoylthiourea derivative with a triazinethione moiety: Synthesis and coordination with the organometallic fac-[Re(CO)3]+ core
A novel benzoylthiourea derivative with a triazinethione moiety: Synthesis and coordination with the organometallic fac-[Re(CO)3]+ core
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Mukiza, J., Braband, H., Bolliger, R., Blacque, O., Alberto, R., & Nkurunziza, J. B. (2021). A novel benzoylthiourea derivative with a triazinethione moiety: Synthesis and coordination with the organometallic fac-[Re(CO)3]+ core. Inorganica Chimica Acta, 516, 120116. https://doi.org/10.1016/j.ica.2020.120116
Abstract
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Abstract
Benzoylthiourea derivatives containing heterocyclic moiety strongly coordinate and stabilize the organometallic fac-Re(CO3 core forming both monomer and multimer organorhenium(I) complexes. The reaction of isophthaloyl dichloride with potassium thiocyanate in acetone followed by addition of diphenylamine led to a novel benzoylthiourea derivative with triazinethione moiety ligand, typically 3-(4-(diphenylamino)-6-thioxo-1,6-dihydro-1,3,5-triazin-2-yl)N(diphenylcarbamothioyebenzamide (H2L). The purity and retention time of the liga
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- Mukiza, Janvier
- Braband, Henrik
- Bolliger, Robin
- Alberto, Roger
- Nkurunziza, Jean Baptiste
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Mukiza, J., Braband, H., Bolliger, R., Blacque, O., Alberto, R., & Nkurunziza, J. B. (2021). A novel benzoylthiourea derivative with a triazinethione moiety: Synthesis and coordination with the organometallic fac-[Re(CO)3]+ core. Inorganica Chimica Acta, 516, 120116. https://doi.org/10.1016/j.ica.2020.120116
