Publication: One Electron Changes Everything: Synthesis, Characterization, and Reactivity Studies of [Re(NCCH3)6]3+
One Electron Changes Everything: Synthesis, Characterization, and Reactivity Studies of [Re(NCCH3)6]3+
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Bolliger, R., Blacque, O., Braband, H., & Alberto, R. (2022). One Electron Changes Everything: Synthesis, Characterization, and Reactivity Studies of [Re(NCCH3)6]3+. Inorganic Chemistry, 61(46), 18325–18334. https://doi.org/10.1021/acs.inorgchem.2c02056
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Oxidation of [Re(NCCH3)6]2+ with the thianthrene radical cation results in the formation of [Re(NCCH3)6]3+, one of the very rare cases of a fully solvated +3 complex. It was fully characterized by spectroscopy and X-ray structure analysis. In contrast to its reduced analogue, [Re(NCCH3)6]3+ exhibits a much faster CH3CN exchange. Hence, substitution reactions proceed at 20 °C within minutes. Its potential as a versatile precursor for ReIII chemistry was examined with a series of substitution reactions. The more lipophilic analogue [Re(
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- Bolliger, Robin
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Bolliger, R., Blacque, O., Braband, H., & Alberto, R. (2022). One Electron Changes Everything: Synthesis, Characterization, and Reactivity Studies of [Re(NCCH3)6]3+. Inorganic Chemistry, 61(46), 18325–18334. https://doi.org/10.1021/acs.inorgchem.2c02056
