Publication: Exploring preliminary structural relationships and mitochondrial targeting of fac-[MI(CO)3]-bis(diarylphosphino)alkylamine complexes (M = 99Tc, Re)
Exploring preliminary structural relationships and mitochondrial targeting of fac-[MI(CO)3]-bis(diarylphosphino)alkylamine complexes (M = 99Tc, Re)
Date
Date
Date
Citations
Kama, D. V., Frei, A., Schutte-Smith, M., Brink, A., Swart, C., Braband, H., Alberto, R., & Roodt, A. (2021). Exploring preliminary structural relationships and mitochondrial targeting of fac-[MI(CO)3]-bis(diarylphosphino)alkylamine complexes (M = 99Tc, Re). New Journal of Chemistry, 45(47), 22141–22149. https://doi.org/10.1039/d1nj04273d
Abstract
Abstract
Abstract
Two bidentate PNP ligands N,N-bis(di-p-tolylphosphino)cyclohexylamine (Cy-pTolPNP) (1) and N,N-bis(di-p-tolylphosphino)cyclobutylamine (Cb-pTolPNP) (2) were synthesized and crystallized. Coordination to the fac-[MI(CO)3]+ core (M = Re, 99Tc) yielded fac-[Re(Cy-pTolPNP)(CO)3Br] (1A), fac-[99Tc(Cy-pTolPNP)(CO)3Cl] (1B), fac-[Re(Cb-pTolPNP)(CO)3Br] (2A) and fac-[99Tc(Cb-pTolPNP)(CO)3Cl] (2B) in relatively good yields (56 to 86%): The structures of 1, 2, 1A and 1B were studied by single crystal X-ray crystallography. Preliminary mitochond
Metrics
Views
Additional indexing
Creators (Authors)
- Kama, Dumisani V
- Frei, Angelo
- Schutte-Smith, Marietjie
- Brink, Alice
- Swart, Chantel
- Roodt, Andreas
Volume
Volume
Volume
Number
Number
Number
Page range/Item number
Page range/Item number
Page range/Item number
Page end
Page end
Page end
Item Type
Item Type
Item Type
In collections
Dewey Decimal Classifikation
Dewey Decimal Classifikation
Dewey Decimal Classifikation
Keywords
Language
Language
Language
Publication date
Publication date
Publication date
Date available
Date available
Date available
ISSN or e-ISSN
ISSN or e-ISSN
ISSN or e-ISSN
OA Status
OA Status
OA Status
Publisher DOI
Metrics
Views
Citations
Kama, D. V., Frei, A., Schutte-Smith, M., Brink, A., Swart, C., Braband, H., Alberto, R., & Roodt, A. (2021). Exploring preliminary structural relationships and mitochondrial targeting of fac-[MI(CO)3]-bis(diarylphosphino)alkylamine complexes (M = 99Tc, Re). New Journal of Chemistry, 45(47), 22141–22149. https://doi.org/10.1039/d1nj04273d