Publication: Novel Synthesis of 2-Alkylquinolizinium-1-olates and their 1,3-Dipolar Cycloaddition reactions with Acetylenes
Date
Date
Date
2012
Journal Article
Published version
Abstract
Abstract
Abstract
Several 2-alkylquinolizinium-1-olates 9, i.e., heterobetaines, were prepared from ketone 11, the latter being readily available either from pyridine-2-carbaldehyde via a Grignard reaction, followed by oxidation with MnO2, or from 2-picolinic acid (= pyridine-2-carboxylic acid) via the corresponding Weinreb amide and subsequent Grignard reaction. Mesoionic heterobetaines such as quinolizinium derivatives have the potential to undergo cycloaddition reactions with double and triple bonds, e.g., 1,3-dipolar cycloadditions or Diels-Alder r
Additional indexing
Creators (Authors)
- Gebert, Andreas
- Barth, Max
- Widmer, Ulrich
- Heimgartner, Heinz
Volume
Volume
Volume
95
Number
Number
Number
5
Page range/Item number
Page range/Item number
Page range/Item number
737
Page end
Page end
Page end
760
Item Type
Item Type
Item Type
Journal Article
In collections
Dewey Decimal Classifikation
Dewey Decimal Classifikation
Dewey Decimal Classifikation
Language
Language
Language
English
Publication date
Publication date
Publication date
2012-05-21
Date available
Date available
Date available
2012-05-22
ISSN or e-ISSN
ISSN or e-ISSN
ISSN or e-ISSN
0018-019X
OA Status
OA Status
OA Status
Green
Publisher DOI
Green Open Access
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Permanent URL
Files
Files
Files
Files available to download:2
Files
Files
Files
Files available to download:2