Publication: Solvent-Controlled Morphology of Catalytic Monolayers at Solid–Liquid Interfaces
Solvent-Controlled Morphology of Catalytic Monolayers at Solid–Liquid Interfaces
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Kraack, J. P., & Hamm, P. (2018). Solvent-Controlled Morphology of Catalytic Monolayers at Solid–Liquid Interfaces. Journal of Physical Chemistry C, 122(4), 2259–2267. https://doi.org/10.1021/acs.jpcc.7b12421
Abstract
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Abstract
Ultrafast vibrational dynamics of monolayers from a rhenium carbonyl complex at solid−liquid interfaces is investigated with the help of 2D ATR IR spectroscopy in dependence of the solvation environment. By changing the solvent from methanol to acetonitrile, we observe a structural transition between two states and find that this transition is fully reversible. The two coexisting states are identified by distinct but closely spaced (∼15 cm−1) vibrational bands in the region of the A′(1) symmetric carbonyl stretch vibration. Surface-di
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- Kraack, Jan Philip
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Kraack, J. P., & Hamm, P. (2018). Solvent-Controlled Morphology of Catalytic Monolayers at Solid–Liquid Interfaces. Journal of Physical Chemistry C, 122(4), 2259–2267. https://doi.org/10.1021/acs.jpcc.7b12421
