Publication: Monocyclometalated (C N) Gold(III) Metallacycles: Tunable Emission and Singlet Oxygen (1O2) Generation Properties
Monocyclometalated (C N) Gold(III) Metallacycles: Tunable Emission and Singlet Oxygen (1O2) Generation Properties
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Malmberg, R., Suter, D., Blacque, O., & Venkatesan, K. (2021). Monocyclometalated (C N) Gold(III) Metallacycles: Tunable Emission and Singlet Oxygen (1O2) Generation Properties. Chemistry, 27(58), 14410–14417. https://doi.org/10.1002/chem.202102331
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The synthesis, characterization and photoluminescent properties of four cyclometalated (C N)-type gold(III) complexes bearing a bidentate diacetylide ligand, tolan-2,2'-diacetylide (tda), are reported. The complexes exhibit highly tunable excited state properties and show photoluminescence (PL) across the entire visible spectrum from sky-blue (lambda(PL)=493 nm) to red (lambda(PL)=675 nm) with absolute PL quantum yields (PLQY) of up to 75 % in solution, the highest PLQY found for any monocyclometalated Au(III) complex in solution. As
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Malmberg, R., Suter, D., Blacque, O., & Venkatesan, K. (2021). Monocyclometalated (C N) Gold(III) Metallacycles: Tunable Emission and Singlet Oxygen (1O2) Generation Properties. Chemistry, 27(58), 14410–14417. https://doi.org/10.1002/chem.202102331