Publication:

Monocyclometalated (C N) Gold(III) Metallacycles: Tunable Emission and Singlet Oxygen (1O2) Generation Properties

Date

Date

Date
2021
Journal Article
Published version

Citations

Citation copied

Malmberg, R., Suter, D., Blacque, O., & Venkatesan, K. (2021). Monocyclometalated (C N) Gold(III) Metallacycles: Tunable Emission and Singlet Oxygen (1O2) Generation Properties. Chemistry, 27(58), 14410–14417. https://doi.org/10.1002/chem.202102331

Abstract

Abstract

Abstract

The synthesis, characterization and photoluminescent properties of four cyclometalated (C N)-type gold(III) complexes bearing a bidentate diacetylide ligand, tolan-2,2'-diacetylide (tda), are reported. The complexes exhibit highly tunable excited state properties and show photoluminescence (PL) across the entire visible spectrum from sky-blue (lambda(PL)=493 nm) to red (lambda(PL)=675 nm) with absolute PL quantum yields (PLQY) of up to 75 % in solution, the highest PLQY found for any monocyclometalated Au(III) complex in solution. As

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40 since deposited on 2022-01-13
Acq. date: 2025-11-14

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Creators (Authors)

Journal/Series Title

Journal/Series Title

Journal/Series Title

Volume

Volume

Volume
27

Number

Number

Number
58

Page range/Item number

Page range/Item number

Page range/Item number
14410

Page end

Page end

Page end
14417

Item Type

Item Type

Item Type
Journal Article

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Dewey Decimal Classifikation

Dewey Decimal Classifikation

Keywords

General Chemistry, Catalysis, Organic Chemistry

Language

Language

Language
English

Publication date

Publication date

Publication date
2021-10-19

Date available

Date available

Date available
2022-01-13

Publisher

Publisher

Publisher

ISSN or e-ISSN

ISSN or e-ISSN

ISSN or e-ISSN
0947-6539

OA Status

OA Status

OA Status
Closed

Metrics

Views

40 since deposited on 2022-01-13
Acq. date: 2025-11-14

Citations

Citation copied

Malmberg, R., Suter, D., Blacque, O., & Venkatesan, K. (2021). Monocyclometalated (C N) Gold(III) Metallacycles: Tunable Emission and Singlet Oxygen (1O2) Generation Properties. Chemistry, 27(58), 14410–14417. https://doi.org/10.1002/chem.202102331

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