Publication: Synthese und Struktur von Zink-Komplexen von 2-Amino-1-azetinen
Synthese und Struktur von Zink-Komplexen von 2-Amino-1-azetinen
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Stierli, F., Prewo, R., Bieri, J. H., & Heimgartner, H. (1984). Synthese und Struktur von Zink-Komplexen von 2-Amino-1-azetinen. Helvetica Chimica Acta, 67, 927–933. https://doi.org/10.1002/hlca.19840670402
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Synthesis and Structure of Zinc Complexes of 2-Amino-1-azetines The 2-dimethylamino-3,3-dimethyl-1-azetines 7a and 7b have been synthesized in analogy to the procedure reported by Ghosez et al. [1] (Scheme 1). The crystal structure of 1-benzhydryl-azetidindimethyliminiumchloride 5a, a precursor of azetine 7a, has been established by X-ray diffraction analysis. Treatment of azetines 7a and 7b with ZnBr, in CH2Cl2/MeCN yielded tetrahedral bis(azetine)dibromozinc complexes 8a and 8b, respectively (Scheme 2). The molecular structure of 8a
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Stierli, F., Prewo, R., Bieri, J. H., & Heimgartner, H. (1984). Synthese und Struktur von Zink-Komplexen von 2-Amino-1-azetinen. Helvetica Chimica Acta, 67, 927–933. https://doi.org/10.1002/hlca.19840670402