Publication: Analogues of Cis- and Transplatin with a Rich Solution Chemistry:cis-[PtCl2(NH3)(1-MeC-N3)] andtrans-[PtI2(NH3)(1-MeC-N3)]
Analogues of Cis- and Transplatin with a Rich Solution Chemistry:cis-[PtCl2(NH3)(1-MeC-N3)] andtrans-[PtI2(NH3)(1-MeC-N3)]
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Siebel, S., Dammann, C., Sanz Miguel, P. J., Drewello, T., Kampf, G., Teubner, N., Bednarski, P. J., Freisinger, E., & Lippert, B. (2015). Analogues of Cis- and Transplatin with a Rich Solution Chemistry:cis-[PtCl2(NH3)(1-MeC-N3)] andtrans-[PtI2(NH3)(1-MeC-N3)]. Chemistry, 21(49), 17827–17843. https://doi.org/10.1002/chem.201502691
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Abstract
Mono(nucleobase) complexes of the general composition cis-[PtCl2(NH3)L] with L=1-methylcytosine, 1-MeC (1 a) and L=1-ethyl-5-methylcytosine, as well as trans-[PtX2(NH3)(1-MeC)] with X=I (5 a) and X=Br (5 b) have been isolated and were characterized by X-ray crystallography. The Pt coordination occurs through the N3 atom of the cytosine in all cases. The diaqua complexes of compounds 1 a and 5 a, cis-[Pt(H2O)2(NH3)(1-MeC)]2+ and trans-[Pt(H2O)2(NH3)(1-MeC)]2+, display a rich chemistry in aqueous solution, which is dominated by extensiv
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- Siebel, Sabine
- Dammann, Claudia
- Sanz Miguel, Pablo J
- Drewello, Thomas
- Kampf, Gunnar
- Teubner, Natascha
- Bednarski, Patrick J
- Lippert, Bernhard
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Siebel, S., Dammann, C., Sanz Miguel, P. J., Drewello, T., Kampf, G., Teubner, N., Bednarski, P. J., Freisinger, E., & Lippert, B. (2015). Analogues of Cis- and Transplatin with a Rich Solution Chemistry:cis-[PtCl2(NH3)(1-MeC-N3)] andtrans-[PtI2(NH3)(1-MeC-N3)]. Chemistry, 21(49), 17827–17843. https://doi.org/10.1002/chem.201502691