Publication: Induced $fac-mer$ rearrangements in {M(CO)$_3$}$^{+}$ complexes (M = Re, $^{99(m)}$Tc) by a PNP ligand
Induced $fac-mer$ rearrangements in {M(CO)$_3$}$^{+}$ complexes (M = Re, $^{99(m)}$Tc) by a PNP ligand
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Besmer, M. L., Schwitter, F., Battistin, F., Braband, H., Fox, T., Spingler, B., & Alberto, R. (2024). Induced $fac-mer$ rearrangements in {M(CO)$_3$}$^{+}$ complexes (M = Re, $^{99(m)}$Tc) by a PNP ligand. Dalton Transactions, 53(4), 1434–1438. https://doi.org/10.1039/d3dt03992g
Abstract
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Abstract
The fac–mer isomerisation in [MX${3}$(CO)${3}$]$^{2−}$ (M = Re, $^{99}$Tc) is induced by a PNP pincer-type ligand in the presence of a halide scavenger. The adaptation to the aqueous and saline chemistry of $^{99m}$Tc yields mer-[$^{99m}$Tc(PNP)(CO)$_{3}$]$^{+}$.
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- Besmer, Manuel Luca
- Schwitter, Flurina
- Battistin, Federica
- Fox, Thomas
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Besmer, M. L., Schwitter, F., Battistin, F., Braband, H., Fox, T., Spingler, B., & Alberto, R. (2024). Induced $fac-mer$ rearrangements in {M(CO)$_3$}$^{+}$ complexes (M = Re, $^{99(m)}$Tc) by a PNP ligand. Dalton Transactions, 53(4), 1434–1438. https://doi.org/10.1039/d3dt03992g
