Publication: Syntheses, structural characterization and CO releasing properties of boranocarbonate H3BCO2H](-) derivatives
Syntheses, structural characterization and CO releasing properties of boranocarbonate H3BCO2H](-) derivatives
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Pitchumony, T. S., Spingler, B., Motterlini, R., & Alberto, R. (2010). Syntheses, structural characterization and CO releasing properties of boranocarbonate H3BCO2H](-) derivatives. Organic & Biomolecular Chemistry, 8, 4849–4854. https://doi.org/10.1039/c0ob00099j
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CO plays an important role in biological processes and molecules which release CO in a controllable way could therefore be used for medicinal purposes. Beside organometallic carbonyl complexes, boranocarbonate H3BCO2H](-) is one of the most promising candidates but releases CO too rapidly. In order to delay the CO release, we have prepared boranocarbamates H3BCONH-R] from H3BCO2H] which comprise histamine, morpholine, aniline and ethylene-diamine bound via amides to the {H3BCO} moiety. The syntheses of the new derivatives is described
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- Pitchumony, T S
- Motterlini, R
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Pitchumony, T. S., Spingler, B., Motterlini, R., & Alberto, R. (2010). Syntheses, structural characterization and CO releasing properties of boranocarbonate H3BCO2H](-) derivatives. Organic & Biomolecular Chemistry, 8, 4849–4854. https://doi.org/10.1039/c0ob00099j