Publication: Ni-Catalyzed Reductive Dicarbofunctionalization of Nonactivated Alkenes: Scope and Mechanistic Insights
Ni-Catalyzed Reductive Dicarbofunctionalization of Nonactivated Alkenes: Scope and Mechanistic Insights
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Shu, W., García-Domínguez, A., Quirós, M. T., Mondal, R., Cárdenas, D. J., & Nevado, C. (2019). Ni-Catalyzed Reductive Dicarbofunctionalization of Nonactivated Alkenes: Scope and Mechanistic Insights. Journal of the American Chemical Society, 141(35), 13812–13821. https://doi.org/10.1021/jacs.9b02973
Abstract
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Abstract
Olefins devoid of directing or activating groups have been dicarbofunctionalized here with two electrophilic carbon sources under reductive conditions. Simultaneous formation of one C(sp3)-C(sp3) and one C(sp3)-C(sp2) bond across a variety of unbiased π-systems proceeds with exquisite selectivity by the combination of a Ni catalyst with TDAE as sacrificial reductant. Control experiments and computational studies revealed the feasibility of a radical-based mechanism involving, formally, two interconnected Ni(I)/Ni(III) processes and de
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- Shu, Wei
- García-Domínguez, Andrés
- Quirós, M Teresa
- Mondal, Rahul
- Cárdenas, Diego J
- Nevado, Cristina
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Shu, W., García-Domínguez, A., Quirós, M. T., Mondal, R., Cárdenas, D. J., & Nevado, C. (2019). Ni-Catalyzed Reductive Dicarbofunctionalization of Nonactivated Alkenes: Scope and Mechanistic Insights. Journal of the American Chemical Society, 141(35), 13812–13821. https://doi.org/10.1021/jacs.9b02973
