Publication: Structural Diversity in Thallium Chemistry. Part VI. Analysis of Structure Correlation in Organoammonium Bromothallates(III)
Structural Diversity in Thallium Chemistry. Part VI. Analysis of Structure Correlation in Organoammonium Bromothallates(III)
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Linden, A., Petridis, A., & James, B. D. (2009). Structural Diversity in Thallium Chemistry. Part VI. Analysis of Structure Correlation in Organoammonium Bromothallates(III). Helvetica Chimica Acta, 92, 29–71. https://doi.org/10.1002/hlca.200800316
Abstract
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New bromothallate(III) complexes have been synthesized using eleven organoammonium cations related to others employed previously. The crystal structure determinations of eight of these have been performed. The diethylenetriammonium cation yields the first compound containing [TlBr6]3 as the only anionic species, while the N,N,N’,N’’,N’’-pentamethyldiethylenetriammonium cation gave a mixed salt containing discrete [TlBr4] and Br ions, in which the [TlBr4] unit does not participate in hydrogen bonding. In the pyrazolinium mixed salt
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- Petridis, A
- James, B D
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Linden, A., Petridis, A., & James, B. D. (2009). Structural Diversity in Thallium Chemistry. Part VI. Analysis of Structure Correlation in Organoammonium Bromothallates(III). Helvetica Chimica Acta, 92, 29–71. https://doi.org/10.1002/hlca.200800316
