Publication: Two new spermidine alkaloids from Chisocheton weinlandii
Two new spermidine alkaloids from Chisocheton weinlandii
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Tzouros, M., Bigler, L., Bienz, S., Hesse, M., Inada, A., Murata, H., Inatomi, Y., Nakanishi, T., & Darnaedi, D. (2004). Two new spermidine alkaloids from Chisocheton weinlandii. Helvetica Chimica Acta, 87(6), 1411–1425. https://doi.org/10.1002/hlca.200490129
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The investigation of the MeOH extract of the leaves of Chisocheton weinlandii Harms (Meliaceae) revealed two new open-chain spermidine alkaloids, chisitine 1 (1) and chisitine 2 (2). Their structures were elucidated by NMR spectroscopy, tandem-mass spectrometry, and independant syntheses (Scheme 3). Detailed MS/MS fragmentation pathways are discussed for both compounds based on H/D exchange and 18O-labeling experiments (Schemes 1 and 2).
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Tzouros, M., Bigler, L., Bienz, S., Hesse, M., Inada, A., Murata, H., Inatomi, Y., Nakanishi, T., & Darnaedi, D. (2004). Two new spermidine alkaloids from Chisocheton weinlandii. Helvetica Chimica Acta, 87(6), 1411–1425. https://doi.org/10.1002/hlca.200490129