Publication: New approach for the synthesis of water soluble fac-[MI(CO)3]+ bis(diarylphosphino)alkylamine complexes (M = 99Tc, Re)
New approach for the synthesis of water soluble fac-[MI(CO)3]+ bis(diarylphosphino)alkylamine complexes (M = 99Tc, Re)
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Kama, D. V., Frei, A., Brink, A., Braband, H., Alberto, R., & Roodt, A. (2021). New approach for the synthesis of water soluble fac-[MI(CO)3]+ bis(diarylphosphino)alkylamine complexes (M = 99Tc, Re). Dalton Transactions, 50, 17506–17514. https://doi.org/10.1039/d1dt03234h
Abstract
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Abstract
A novel proof-of-concept is reported to modify the water solubility and potential biological effects of a bis(diphenylphosphino)alkylamine (PNP) ligand and the corresponding metal complex, by introducing an amine group on the outer periphery of the pendant ligand arm. Thus, a tertiary butoxycarbonyl protected N’-Boc-ethylenediamine-N,N-bis(diphenylphosphino) (N‘-Boc-PNP) ligand (1) was synthesized by reacting the protected ethylenediamine and chlorodiphenylphosphine in a 1 : 2 molar ratio. The corresponding fac-[Re(CO)3(N‘-Boc-PNP)Br]
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Creators (Authors)
- Kama, Dumisani V
- Frei, Angelo
- Brink, Alice
- Roodt, Andreas
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Kama, D. V., Frei, A., Brink, A., Braband, H., Alberto, R., & Roodt, A. (2021). New approach for the synthesis of water soluble fac-[MI(CO)3]+ bis(diarylphosphino)alkylamine complexes (M = 99Tc, Re). Dalton Transactions, 50, 17506–17514. https://doi.org/10.1039/d1dt03234h
