Publication: Gram-Scale Synthesis and Supramolecular Complex of Precursors of Clar’s Hydrocarbon Triangulene
Gram-Scale Synthesis and Supramolecular Complex of Precursors of Clar’s Hydrocarbon Triangulene
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Ribar, P., Šolomek, T., & Juricek, M. (2019). Gram-Scale Synthesis and Supramolecular Complex of Precursors of Clar’s Hydrocarbon Triangulene. Organic Letters, 21(17), 7124–7128. https://doi.org/10.1021/acs.orglett.9b02683
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We present to date the most efficient gramscale synthesis of triangulene-4,8-dione and 12-hydroxytriangulene- 4,8-dione, the precursors of Clar’s hydrocarbon, in overall yields >50%. The direct dihydroprecursors of triangulene, obtained upon reduction of triangulene-4,8- dione, were stabilized in a supramolecular complex with a tetracationic cyclophane ExBox4+ and characterized by singlecrystal X-ray crystallography. This result represents the first step in an endeavor to stabilize the fragile core of triangulene in an inclusion compl
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- Ribar, Peter
- Šolomek, Tomáš
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Ribar, P., Šolomek, T., & Juricek, M. (2019). Gram-Scale Synthesis and Supramolecular Complex of Precursors of Clar’s Hydrocarbon Triangulene. Organic Letters, 21(17), 7124–7128. https://doi.org/10.1021/acs.orglett.9b02683
