Publication: Deuteration of heptamethine cyanine dyes enhances their emission efficacy
Deuteration of heptamethine cyanine dyes enhances their emission efficacy
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Janeková, H., Friedman, H. C., Russo, M., Zyberaj, M., Ahmed, T., Hua, A. S., Sica, A. V., Caram, J. R., & Stacko, P. (2024). Deuteration of heptamethine cyanine dyes enhances their emission efficacy. Chemical Communications, 60(8), 1000–1003. https://doi.org/10.1039/d3cc05153f
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The design of bright short-wave infrared fluorophores remains a grand challenge. Here we investigate the impact of deuteration on the properties in a series of heptamethine dyes, the absorption of which spans near-infrared and SWIR regions. We demonstrate that it is a generally applicable strategy that leads to enhanced quantum yields of fluorescence, longer-lived singlet excited states and suppressed rates of non-radiative deactivation processes.
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Janeková, H., Friedman, H. C., Russo, M., Zyberaj, M., Ahmed, T., Hua, A. S., Sica, A. V., Caram, J. R., & Stacko, P. (2024). Deuteration of heptamethine cyanine dyes enhances their emission efficacy. Chemical Communications, 60(8), 1000–1003. https://doi.org/10.1039/d3cc05153f