Publication: Two-Nanometer voids in single-layer hexagonal Boron Nitride: Formation via the "Can-Opener" effect and annihilation by self-healing
Two-Nanometer voids in single-layer hexagonal Boron Nitride: Formation via the "Can-Opener" effect and annihilation by self-healing
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Cun, H., Iannuzzi, M., Hemmi, A., Osterwalder, J., & Greber, T. (2014). Two-Nanometer voids in single-layer hexagonal Boron Nitride: Formation via the “Can-Opener” effect and annihilation by self-healing. ACS Nano, 8(7), 7423–7431. https://doi.org/10.1021/nn502645w
Abstract
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The exposure of hexagonal boron nitride single layers to low energy ions leads to the formation of vacancy defects that are mobile at elevated temperatures. For the case of h-BN on rhodium, a superhoneycomb surface with 3 nm lattice constant (nanomesh), a concerted self-assembly of these defects is observed, where the “can-opener” effect leads to the cut-out of 2 nm “lids” and stable voids in the h-BN layer. These clean-cut voids repel each other, which enables the formation of arrays with a nearest neighbor distance down to about 8 n
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Cun, H., Iannuzzi, M., Hemmi, A., Osterwalder, J., & Greber, T. (2014). Two-Nanometer voids in single-layer hexagonal Boron Nitride: Formation via the “Can-Opener” effect and annihilation by self-healing. ACS Nano, 8(7), 7423–7431. https://doi.org/10.1021/nn502645w