Publication: 3d–4f {CoII3Ln(OR)4} Cubanes as Bio-Inspired Water Oxidation Catalysts
Date
Date
Date
2015
Journal Article
Published version
Abstract
Abstract
Abstract
Although the {CaMn4O5} oxygen evolving complex (OEC) of photosystem II is a major paradigm for water oxidation catalyst (WOC) development, the comprehensive translation of its key features into active molecular WOCs remains challenging. The [CoII3Ln(hmp)4(OAc)5H2O] ({CoII3Ln(OR)4}; Ln = Ho–Yb, hmp = 2-(hydroxymethyl)pyridine) cubane WOC series is introduced as a new springboard to address crucial design parameters, ranging from nuclearity and redox-inactive promoters to operational stability and ligand exchange properties. The {CoII3L
Metrics
Views
212 since deposited on 2016-01-13
Acq. date: 2025-11-12
Additional indexing
Creators (Authors)
- Evangelisti, Fabio
- Moré, René
- Hodel, Florian
- Luber, Sandra
Journal/Series Title
Journal/Series Title
Journal/Series Title
Volume
Volume
Volume
137
Number
Number
Number
34
Page range/Item number
Page range/Item number
Page range/Item number
11076
Page end
Page end
Page end
11084
Item Type
Item Type
Item Type
Journal Article
Dewey Decimal Classifikation
Dewey Decimal Classifikation
Dewey Decimal Classifikation
Language
Language
Language
English
Publication date
Publication date
Publication date
2015-09-02
Date available
Date available
Date available
2016-01-13
ISSN or e-ISSN
ISSN or e-ISSN
ISSN or e-ISSN
0002-7863
OA Status
OA Status
OA Status
Closed
Publisher DOI
Metrics
Views
212 since deposited on 2016-01-13
Acq. date: 2025-11-12
Closed
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