Publication: The reaction of oxidorhenium(v) with dipodal and tripodal aroylhydrazines: formation of dinuclear and trinuclear aroylhydrazone-bridged rhenium(v) complexes
The reaction of oxidorhenium(v) with dipodal and tripodal aroylhydrazines: formation of dinuclear and trinuclear aroylhydrazone-bridged rhenium(v) complexes
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Mukiza, J., Blacque, O., Habarurema, G., & Kampire, E. (2020). The reaction of oxidorhenium(v) with dipodal and tripodal aroylhydrazines: formation of dinuclear and trinuclear aroylhydrazone-bridged rhenium(v) complexes. New Journal of Chemistry, 44(17), 7080–7090. https://doi.org/10.1039/d0nj00182a
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The chemistry of aroylhydrazines has been attracting attention mainly due to the residual functional group, -CONH-NH2, which has important effects on hydrophilicity and has the potential to provide special interaction sites for targeting molecules. The reaction of a dipodal aroylhydrazine, typically isophthalohydrazide (isphz), with trans-[ReOX3(PPh3)(2)] in acetone led to the isolation of ligand-bridged oxidorhenium(v) dinuclear complexes (mu-dphz)ReOX2(PPh3), (X = Cl (1), Br (2). The novel dianion dipodal aroylhydrazone Schiff
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- Mukiza, Janvier
- Habarurema, Gratien
- Kampire, Edwige
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Mukiza, J., Blacque, O., Habarurema, G., & Kampire, E. (2020). The reaction of oxidorhenium(v) with dipodal and tripodal aroylhydrazines: formation of dinuclear and trinuclear aroylhydrazone-bridged rhenium(v) complexes. New Journal of Chemistry, 44(17), 7080–7090. https://doi.org/10.1039/d0nj00182a