Publication: Nonacethrene Unchained: A Cascade to Chiral Contorted Conjugated Hydrocarbon with Two sp3-Defects
Nonacethrene Unchained: A Cascade to Chiral Contorted Conjugated Hydrocarbon with Two sp3-Defects
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Čavlović, D., Häussinger, D., Blacque, O., Ravat, P., & Juricek, M. (2022). Nonacethrene Unchained: A Cascade to Chiral Contorted Conjugated Hydrocarbon with Two sp3-Defects. JACS Au, 2(7), 1616–1626. https://doi.org/10.1021/jacsau.2c00190
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We demonstrate that structurally complex carbon nanostructures can be achieved via a synthetic approach that capitalizes on a π-radical reaction cascade. The cascade is triggered by oxidation of a dihydro precursor of helical diradicaloid nonacethrene to give a chiral contorted polycyclic aromatic hydrocarbon named hypercethrene. In this ten-electron oxidation process, four σ-bonds, one π-bond, and three six-membered rings are formed in a sequence of up to nine steps to yield a 72-carbon-atom warped framework, comprising two configura
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- Čavlović, Daniel
- Häussinger, Daniel
- Ravat, Prince
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Čavlović, D., Häussinger, D., Blacque, O., Ravat, P., & Juricek, M. (2022). Nonacethrene Unchained: A Cascade to Chiral Contorted Conjugated Hydrocarbon with Two sp3-Defects. JACS Au, 2(7), 1616–1626. https://doi.org/10.1021/jacsau.2c00190
