Publication: A closer look into the distance dependence of vibrational energy transfer on surfaces using 2D IR spectroscopy
A closer look into the distance dependence of vibrational energy transfer on surfaces using 2D IR spectroscopy
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Fernández-Terán, R., & Hamm, P. (2020). A closer look into the distance dependence of vibrational energy transfer on surfaces using 2D IR spectroscopy. Journal of Chemical Physics, 153, 154706. https://doi.org/10.1063/5.0025787
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Vibrational energy transfer (VET) between two isotopologues of [Re(dcb)(CO)3Br] immobilized on a TiO2 surface is studied with the help of 2D IR spectroscopy in dependence of surface coverage. To dilute the molecules on the surface, and thereby control the intermolecular distances, two different diluents have been used: a third isotopologue of the same molecule and 4-cyanobenzoic acid. As expected, the VET rate decreases with dilution. For a quantitative investigation of the distance dependence of the VET rate, we analyze the data base
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Fernández-Terán, R., & Hamm, P. (2020). A closer look into the distance dependence of vibrational energy transfer on surfaces using 2D IR spectroscopy. Journal of Chemical Physics, 153, 154706. https://doi.org/10.1063/5.0025787