Publication: [C^N]‐Alkenyl Gold(III) Complexes by Proximal Ring‐Opening of (2‐Pyridyl)alkylidenecyclopropanes: Mechanistic Insights
[C^N]‐Alkenyl Gold(III) Complexes by Proximal Ring‐Opening of (2‐Pyridyl)alkylidenecyclopropanes: Mechanistic Insights
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González, J. A., Verdugo, F., Mascareñas, J. L., López, F., & Nevado, C. (2020). [C^N]‐Alkenyl Gold(III) Complexes by Proximal Ring‐Opening of (2‐Pyridyl)alkylidenecyclopropanes: Mechanistic Insights. Angewandte Chemie Internationale Edition, 59(45), 20049–20054. https://doi.org/10.1002/anie.202007371
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Pyridine‐substituted alkylidenecyclopropanes (Py‐ACPs) react with gold(III) salts under mild reaction conditions through an unprecedented, proximal ring‐opening pathway, to generate highly appealing, catalytically active pyridine alkenyl [C^N]‐gold(III) species. Mechanistic studies reveal that the activation of the C−C bond of the ACP takes place through an unusual concerted, σ‐bond metathesis type‐process.
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- González, Jorge A
- Verdugo, Felipe
- Mascareñas, José Luis
- López, Fernando
- Nevado, Cristina
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González, J. A., Verdugo, F., Mascareñas, J. L., López, F., & Nevado, C. (2020). [C^N]‐Alkenyl Gold(III) Complexes by Proximal Ring‐Opening of (2‐Pyridyl)alkylidenecyclopropanes: Mechanistic Insights. Angewandte Chemie Internationale Edition, 59(45), 20049–20054. https://doi.org/10.1002/anie.202007371
