Publication: Synthesis and structural characterization of LiI, ZnII, CdII, and HgII complexes containing a fluorinated β-diketiminate ligand
Synthesis and structural characterization of LiI, ZnII, CdII, and HgII complexes containing a fluorinated β-diketiminate ligand
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Liu, J., Vieille-Petit, L., Linden, A., Luan, X., & Dorta, R. (2012). Synthesis and structural characterization of LiI, ZnII, CdII, and HgII complexes containing a fluorinated β-diketiminate ligand. Journal of Organometallic Chemistry, 719, 80–86. https://doi.org/10.1016/j.jorganchem.2012.08.028
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The reaction of a fluorinated β-aminoimine compound ArN]C(Me)CH]C(Me)NHAr (1) (Ar = 2,6-F2C6H3) with n-BuLi in coordinating solvents (Et2O and THF) leads to the solvated complexes [HC(CMeNAr)2]Li(Et2O) (2) and [HC(CMeNAr)2]Li(THF) (3), respectively. They exist as momonuclear complexes featuring lithium atoms in a distorted trigonal planar environment. The same reaction, which was then carried out in a non-coordinated solvent (pentane), provided complex [HC(CMeNAr)2]2Li2 (4). It crystallized as a dinuclear complex in the solid state, f
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- Liu, Jingjing
- Vieille-Petit, L
- Luan, X
- Dorta, R
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Liu, J., Vieille-Petit, L., Linden, A., Luan, X., & Dorta, R. (2012). Synthesis and structural characterization of LiI, ZnII, CdII, and HgII complexes containing a fluorinated β-diketiminate ligand. Journal of Organometallic Chemistry, 719, 80–86. https://doi.org/10.1016/j.jorganchem.2012.08.028
